研究室教員†

• 准教授　斎藤　雅一

発表論文†

1. "Synthesis and Structure of Pentaorganostannate Having Five Carbon Substituents", M. Saito, S. Imaizumi, T. Tajima, K. Ishimura and S. Nagase, J. Am. Chem. Soc., 129, 10974-10975 (2007).
2. "Synthesis and Reactions of a Novel Bulky Aryllithium", M. Saito, Y. Okuyama, T. Tajima, D. Kato and M. Yoshioka, Appl. Organomet. Chem., 21, 604-611 (2007).
3. "3,5-Bis(trimethylsilyl)triphenyleno[1,12-bcd]thiophene", M. Saito, T. Tanikawa and T. Tajima, Acta Crystallogr. E., 63, o2923 (2007).
4. "Synthesis and Structures of Polychalcogenadistannabicyclo[k.l.m]alkanes", M. Saito, H. Hashimoto, T. Tajima and M. Ikeda, J. Organomet. Chem., 692, 2729-2735 (2007).
5. "Synthesis and Reactions of Stannole Anions", R. Haga, M. Saito and M. Yoshioka, Eur. J. Inorg. Chem., 1297-1306 (2007).
6. "Reduction of Phenyl Silyl Acetylene with Lithium: Unexpected Formation of a Dilithium Dibenzopentalenide", M. Saito, M. Nakamura, T. Tajima and M. Yoshioka, Angew. Chem., Int. Ed., 46, 1504-1507 (2007). Selected as the Inside Cover
7. "Synthesis and Characterization of Dimetallostannafluorenes", M. Saito, M. Shimosawa, M. Yoshioka, K. Ishimura and S. Nagase, Chem. Lett., 35, 940-941 (2006).
8. "Synthesis of Stannaindenyl Anions and a Dianion", M. Saito, M. Shimosawa, M. Yoshioka, K. Ishimura and S. Nagase, Organometallics, 25, 2967-2971 (2006).
9. "Reversible Redox Behavior Between Stannole Dianion and Bistannole-1,2-dianion", R. Haga, M. Saito and M. Yoshioka, J. Am. Chem. Soc., 128, 4934-4935 (2006).
10. "The Aromaticity of the Stannole Dianion", M. Saito, R. Haga, M. Yoshioka, K. Ishimura and S. Nagase, Angew. Chem., Int. Ed., 44, 6553-6556 (2005).
11. "Silyl Migration in the Photochemical Reaction of 2-Trimethylsilylmethylphenylketones", M. Saito, A. Saito, Y. Ishikawa and M. Yoshioka, Org. Lett., 7, 3139-3141 (2005).
12. "Synthesis and Structures of Bi(1,1-stannole)s", M. Saito, R. Haga and M. Yoshioka, Eur. J. Inorg. Chem., 3750-3755 (2005).
13. "Formation of the Dianion and the Dimer of 9,10-Distannaanthracene", M. Saito, N. Henzan and M. Yoshioka, Chem. Lett., 34, 1018-1019 (2005).
14. "Reduction of Dichlorodiphenylstannane", M. Saito, Y. Okamoto and M. Yoshioka, Appl. Organomet. Chem., 19, 894-897 (2005).
15. "Synthesis and Photochemical Reactions of 1,2,7-Chalcogenadistannacycloheptanes", M. Saito, K. Iso, K. Yamada, S. Nakano and M. Yoshioka, Appl. Organomet. Chem., 19, 551-554 (2005).
16. "Tin-Chalcogen Double-Bond Compounds, Stannanethione and Stannaneselone: Synthesis, Structure, and Reactivities", M. Saito, N. Tokitoh and R. Okazaki, J. Am. Chem. Soc., 126, 15572-15582 (2004).
17. "Synthesis, Structures and Reactions of Novel 9,10-Dihydro-9,10-distannaanthracenes", M. Saito, N. Henzan, M. Nitta and M. Yoshioka, Eur. J. Inorg. Chem., 743-748 (2004).
18. "Synthesis of Stannole Anion by Alkylation of Stannole Dianion", M. Saito, R. Haga and M. Yoshioka, Chem. Lett., 32, 912-913 (2003).

外部資金獲得状況†

1. 2007年度　財団法人住友財団　基礎科学研究助成　新規なジベンゾペンタレンの酸化・還元系の構築と機能性錯体への展開　1,000千円
2. 2006～7年度　財団法人旭硝子財団　自然科学系研究助成　金属間非結合相互作用を有するポリシロキサン及びその関連高分子化合物の合成と物性　2,000千円
3. 2006年度　財団法人実吉奨学会　研究助成金　修飾フラーレンを目指した新規拡張π電子系の合成　1,000千円
4. 2005～6年度　科学研究費補助金若手研究（Ｂ）　斎藤雅一　含スズ芳香族系の創製とその機能化　3,600千円
5. 2005年度　有機合成化学協会　研究企画賞(コニカミノルタテクノロジーセンター研究企画賞)　ヘテロスマネンの系統的合成法の開発と物性化学への展開　500千円
6. 2003年度　財団法人東レ科学振興会　東レ科学技術研究助成　スズを骨格に有する特異なπ電子系の創製と機能性分子への展開　10,000千円