活動報告・予告/Annual Reports/坂本研究室2007 の履歴差分(No.5)


#norelated
*研究室教員 [#v209baae]
*研究室教員 [#zcf8be82]
-准教授 坂本 章

*原著論文(査読あり) [#o7b6f35a]
*原著論文(査読あり) [#s71c6886]
+O. Tsukamoto, M. Villeneuve, A. Sakamoto, H. Nakahara,
"Change in the Orientation and Packing upon Adsorption of Pyranine Molecules onto Cationic Langmuir Monolayers and Langmuir-Blodgett Films",
'''Bull. Chem. Soc. Jpn.''', ''80'', 1723-1730 (2007).
+"Construction of Picosecond Time-resolved Raman Spectrometers with Near-infrared Excitation", A. Sakamoto, S. Matsuno, and M. Tasumi, J. Raman Spectrosc., 37, 429-435, 2006.
+"Comparison of the Raman Spectrum of trans-Stilbene in the S1 State Calculated by the CIS Method and the Spectra Observed under Resonant and Off-resonant Conditions", A. Sakamoto, F. Tanaka, M. Tasumi, H. Torii, K. Kawato, and K. Furuya, Vib. Spectrosc., 42, 176-182, 2006.
+"Time-resolved Fluorescence Spectroscopic and Scanning Near-field Optical Microscopic Studies of Rhodamine Dye Adsorbed in Cationic Langmuir-Blodgett Films", K. Ray, H. Nakahara, A. Sakamoto, Spectrochim. Acta A, 61, 103-107, 2005.
+"Infrared Measurements of Organic Radical Anions in Solution Using Mid-infrared Optical Fibers and Spectral Analyses Based on Density Functional Theory Calculations", A. Sakamoto, M. Kuroda, T. Harada, and M. Tasumi, J. Mol. Struct., 735-736, 3-9, 2005.
+"Transfer of Photoenergy in π-Conjugated Polymers. Two Types of Photoluminescence that Involve Energy Transfer along a Polymer Chain", T. Yamamoto, B.-L. Lee, I. Nurulla, T. Yasuda, I. Yamaguchi, A. Wada, C. Hirose, M. Tasumi, A. Sakamoto, and E. Kobayashi, J. Phys. Chem. B, 109, 10605-10610, 2005.
+"Chemistry of Thiosulfinyl Group (>S=S): Preparation, Structure, and Spectroscopic and Chemical Properties of Cyclic Thionosulfites", Juzo Nakayama, Sanae Yoshida, Yoshiaki Sugihara, and Akira Sakamoto, Helv. Chim. Acta, 88, 1451-1471, 2005.
+"Time-resolved fluorescence spectroscopic and scanning near-field optical microscopic studies of rhodamine dye adsorbed in cationic Langmuir-Blodgett films", Ray, Krishanu; Nakahara, Hiroo; Sakamoto, Akira, Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy(2004),  Volume Date 2005,  61A(1-2),  103-107.,  61A(1-2), 103-107, 2004.
+"Relationship between the Distortion of Polyene Chains from Planarity and the Raman Activity of the In-Phase CH Out-of -Plane Wag", K. Fujimorri, A. Sakamoto, and M. Tasumi, Macromol. Sym., 205(1), 33-46, 2004.
+"Vibrational Spectra and Electron–Vibration Interactions of the Naphthalene Radical Anion: Experimental and Theoretical Study", H. Torii, Y. Ueno, A. Sakamoto, and M. Tasumi, Can. J. Chem., 82(6), 951-963, 2004.
+"A. Reversible Disulfur Monoxide (S2O)-Forming Retro-Diels-Alder Reaction. Disproportionation of S2O to Trithio-Ozone (S3) and Sulfur Dioxide (SO2) and Reactivities of S2O and S3", Juzo Nakayama, Satoshi Aoki, Jun Takayama, Akira Sakamoto, Yoshiaki Sugihara, Akihiko Ishii, J. Am. Chem. Soc., 126, 9085-9093, 2004.
+"Molecular Distortion of trans-Stilbene and the Raman Intensity of the In-Phase CH Out-of-Plane Wag of the Central CH=CH Group", K. Furuya, K. Kawato, H. Yokoyama, A. Sakamoto, and M. Tasumi, J. Phys. Chem. A, 107, 8251-8258, 2003.
+"Structures and Properties of Two Diastereomeric Sulfites Derived from cis-3,4-Di-tert-butylthiolane-3,4-diol and Thionyl Chloride", Sanae Tanaka, Yoshiaki Sugihara, Akira Sakamoto, Akihiko Ishii, and Juzo Nakayama, Heteroatom Chem., 14, 587-595, 2003.
+"Regio- and Stereo-chemistry of Addition of Molecular Bromine to S-Oxidzed Derivatives of 3,4-Di-t-butylthiophene: Exclusive 1,4-Cis-additions", Juzo Nakayama, Tomohiro Furuya, Akihiko Ishii, Akihiko Sakamoto, Takashi Otani, and Yoshiaki Sugihara, Bull. Chem. Soc. Jpn., 76, 619-625, 2003.
+"The Thiosulfinyl Group Serves as a Stereogenic Center and Shows Diamagnetic Anisotropy Similar to the Sulfinyl Group", Sanae Tanaka, Yoshiaki Sugihara, Akira Sakamoto, Akihiko Ishii, and Juzo Nakayama, J. Am. Chem. Soc., 125, 9024-9025, 2003.
+A. Sakamoto, F. Tanaka, M. Tasumi, H. Torii, K. Kawato, and K. Furuya,
"Comparison of the Raman Spectrum of trans-Stilbene in the S1 State Calculated by the CIS Method and the Spectra Observed under Resonant and Off-resonant Conditions",
'''Vib. Spectrosc.''', ''42'', 176-182 (2006).
+A. Sakamoto, S. Matsuno, and M. Tasumi,
"Construction of Picosecond Time-resolved Raman Spectrometers with Near-infrared Excitation",
'''J. Raman Spectrosc.''', ''37'' (Prof. W. Kiefer Special Issue), 429-435 (2006).
+Takakazu Yamamoto, Bang-Lin Lee, Ismayil Nurulla, Takuma Yasuda, Isao Yamaguchi, Akihide Wada, Chiaki Hirose, Mitsuo Tasumi, Akira Sakamoto, and Eiji Kobayashi,
"Transfer of Photoenergy in π-Conjugated Polymers. Two Types of Photoluminescence that Involve Energy Transfer along a Polymer Chain",
'''J. Phys. Chem. B.''', ''109'', 10605-10610 (2005).
+Michio Murata, Kazuhiko Mori, Akira Sakamoto, Masumi Villeneuve, and Hiroo Nakahara,
"Effects of an Amphiphilic Perfluoro-carboxylate on the J-Aggregates of a Long-chain Merocyanine with Chlorine Substituent in the Mixed Monolayers and their Mixed Langmuir-Blodgett Films",
'''Chem. Phys. Lett.''', ''405'', 32-38 (2005).
+Akira Sakamoto, Masahito Kuroda, Tomohisa Harada, and Mitsuo Tasumi,
"Infrared Measurements of Organic Radical Anions in Solution Using Mid-infrared Optical Fibers and Spectral Analyses Based on Density Functional Theory Calculations",
'''J. Mol. Struct.''', ''735-736'' (Prof. H. Takahashi Special Issue), 3-9 (2005).
+Krishanu Ray, Hiroo Nakahara, and Akira Sakamoto,
"Time-resolved Fluorescence Spectroscopic and Scanning Near-field Optical Microscopic Studies of Rhodamine Dye Adsorbed in Cationic Langmuir-Blodgett Films",
'''Spectrochim. Acta A''', ''61'', 103-107 (2005).
+Juzo Nakayama, Sanae Yoshida (Tanaka), Yoshiaki Sugihara, and Akira Sakamoto,
"The Chemistry of the Thiosulfinyl Group: Preparation, Structure, and Spectroscopic and Chemical Properties of Cyclic Thionosulfites",
'''Helvetica Chimica Acta''', ''88'', 1451-1471 (2005).
+Hajime Torii, Yuko Ueno, Akira Sakamoto, and Mitsuo Tasumi,
"Vibrational Spectra and Electron-Vibration Interactions of the Naphthalene Radical Anion: Experimental and Theoretical Study",
'''Can. J. Chem.''', ''82(6)'', 951-963 (2004).
+Kazuki Fujimorri, Akira Sakamoto, and Mitsuo Tasumi,
"Relationship between the Distortion of Polyene Chains from Planarity and the Raman Activity of the In-Phase CH Out-of-Plane Wag",
'''Macromol. Sym.''', ''205(1)'', 33-46 (2004).
+Juzo Nakayama, Satoshi Aoki, Jun Takayama, Akira Sakamoto, Yoshiaki Sugihara, and Akihiko Ishii,
"Reversible Disulfur Monoxide (S2O)-Forming Retro-Diels-Alder Reaction. Disproportionation of S2O to Trithio-Ozone (S3) and Sulfur Dioxide (SO2) and Reactivities of S2O and S3",
'''J. Am. Chem. Soc.''', ''126(29)'', 9085-9093 (2004).
+Sanae Tanaka, Yoshiaki Sugihara, Akira Sakamoto, Akihiko Ishii, and Juzo Nakayama,
"The Thiosulfinyl Group Serves as a Stereogenic Center and Shows Diamagnetic Anisotropy Similar to the Sulfinyl Group",
'''J. Am. Chem. Soc.''', ''125(30)'', 9024-9025 (2003).
+Sanae Tanaka, Yoshiaki Sugihara, Akira Sakamoto, Akihiko Ishii, and Juzo Nakayama,
"Structures and Properties of Two Diastereomeric Cyclic Sulfites Derived from cis-3,4-Di-tert-butylthiolane-3,4-diol and Thionyl Chloride",
'''Heteroatom Chemistry''', ''14(7)'', 587-595 (2003).
+Kazuhiko Furuya, Kouji Kawato, Hiroshi Yokoyama, Akira Sakamoto, and Mitsuo Tasumi,
"Molecular Distortion of trans-Stilbene and the Raman Intensity of the In-Phase CH Out-of-Plane Wag of the Central CH=CH Group",
'''J. Phys. Chem. A.''', ''107'', 8251-8258 (2003).
+Juzo Nakayama, Tomohiro Furuya, Akihiko Ishii, Akira Sakamoto, Takashi 
Otani, and Yoshiaki Sugihara,
"Regio- and Stereo-Chemistry of Addition of Molecular Bromine to S-Oxidized Derivatives of 3,4-Di-t-butylthiophene: Exclusive 1,4-Cis-Additions",
'''Bull. Chem. Soc. Jpn.''', ''76'', 619-625 (2003).

*著書・総説・解説等 [#uca1fba7]
*著書・総説・解説等 [#mf1b0f8d]
+坂本 章,
「7. 赤外分光 7.2. 基本的な測定 7.2.2. 試料の取り扱い」,
「第5版 実験化学講座 分光(I)」(丸善),416-422 (2005).
+坂本 章,
「7. 赤外分光 7.2. 基本的な測定 7.2.3. いろいろな測定」,
「第5版 実験化学講座 分光(I)」(丸善),422-438 (2005).
+坂本 章,
「7. 赤外分光 7.3. 応用測定 7.3.3. 時間分解赤外分光 7.3.3.a. ナノ秒時間分解測定」,
「第5版 実験化学講座 分光(I)」(丸善),450-459 (2005).
+坂本 章(分担執筆),
「第2版 標準化学用語辞典」(日本化学会編,丸善),新規18項目 (2005).
+坂本 章,藤森一希,
「分子軌道計算プログラムGaussian03のパーソナルコンピューター(Linux)での実行とネットワーク並列計算」,
'''MaLS FORUM''', ''2'', 40-43 (2004).
+田隅三生,朽津耕三,細矢治夫,早水紀久子,田辺和俊,森岡義幸,坂本 章,佐藤寿邦,廣田勇二,
「化学データベース」,
「情報知識学会誌」,第13巻 第3号,58-72 (2003).

*特許 [#p4c54dea]
*特許 [#h6406031]
+発明者:増谷 浩二,落合 周吉,東山 尚光,木村 淳一,坂本 章,
出願人:(株)エス・ティ・ジャパン,埼玉大学,
発明の名称:文化財検査装置,
特許出願番号:特願2007-127962,
出願日:2007年5月15日.

*外部資金獲得状況 [#u5abfa7c]
+2006~7年度 特定領域研究 坂本 章 配列制御された共役ポリマーのピコ秒赤外吸収測定と励起電子-分子振動相互作用の解明 2,800千円
+科学研究費補助金 基盤研究(C),平成16~17年度,
坂本 章,「ピコ秒赤外分光法による電子励起二量体分子系における電子–分子振動相互作用の解明」,
3,700 千円(平成16年度:2,500 千円,平成17年度:1,200 千円)
*外部資金獲得状況 [#m9ceafc4]
+科学研究費補助金 特定領域研究「次世代共役ポリマーの超階層制御と革新機能」(公募研究),期間:平成19~20年度,
研究代表者:坂本 章,
研究課題名:配列制御された共役ポリマーのピコ秒赤外吸収測定と励起電子–分子振動相互作用の解明,
研究経費:2,600 千円(平成19年度:1,300 千円,平成20年度:1,300 千円)
+科学研究費補助金 特定領域研究「次世代共役ポリマーの超階層制御と革新機能」(公募研究),期間:平成18年度,
研究代表者:坂本 章,
研究課題名:配列制御された共役ポリマーのピコ秒赤外吸収測定と励起電子–分子振動相互作用の解明,
研究経費:1,500 千円
+革新技術開発研究事業[独立行政法人 科学技術振興機構],期間:平成17年度~平成19年度,
代表者:中川 孝郎((株)エス・ティ・ジャパン),協力研究者:坂本 章,
研究課題名:文化財測定用携帯型ラマンイメージング・顕微赤外分光装置の開発研究,
研究経費(総額):91,860 千円(平成17年度:28,500 千円,平成18年度:35,860 千円,平成19年度:27,500 千円),
受託研究経費(埼玉大学配分額):8,000 千円(平成17年度:2,000 千円,平成18年度:3,200 千円,平成19年度:2,800 千円)
+科学研究費補助金 基盤研究(C),期間:平成16~17年度,
研究代表者:坂本 章,
研究課題名:ピコ秒赤外分光法による電子励起二量体分子系における電子–分子振動相互作用の解明,
研究経費:3,700 千円(平成16年度:2,500 千円,平成17年度:1,200 千円)

*学会等の活動 [#vbd6d97a]
+平成20年1月~ 日本分光学会 企画委員会 委員
+平成17年3月~ 日本分光学会 赤外ラマン分光部会 幹事(会計)
*学会等の活動 [#q5bc5da7]
+平成20年1月~ 日本分光学会 企画委員会 委員
+平成17年3月~ 日本分光学会 赤外ラマン分光部会 幹事(会計)