活動報告・予告 / Annual Reports/石井研究室2007

研究室教員

発表論文

  1. Preparation of 3,3-Di-tert-Butylthiirane trans-1,2-Dioxide and Its Reaction with Platinum(0) Complex to give (Disulfenato)Platinum(II) Complex and Regioselectivity of Oxidation of Related (Sulfenato-thiolato)Platinum Complex. Akihiko Ishii, Masayuki Ohishi, and Norio Nakata Eur. J. Inorg. Chem., 5199-5206 (2007).
  2. Rearrangement of a (Dithiolato)PtII Complex Formed by Reaction of a Cyclic Disulfide, 5,6-Dithiabicyclo[4.2.1]nona-1,3-diene, with a Platinum(0) Complex. Oxidation of the Rearranged (Dithiolato)PtII Complex. Akihiko Ishii, Satoshi Kashiura, Yuichi Hayashi, and Wolfgang Weigand Chem. Eur. J., 13, 4326-4333 (2007).
  3. Preparation of a New 1,2,3-Trithiolane, trans-9,10,11-Trithiabicyclo[6.3.0]undecane, and Its Oxidation Reactions. Akihiko Ishii, Manami Suzuki, and Remi Yamashita Tetrahedron, 62, 5441-5447 (2006).
  4. Synthesis and Properties of a Dithiirane trans-1,2-Dioxide, a Three-Membered vic-Disulfoxide. Akihiko Ishii, Masayuki Ohishi, Kimiyo Matsumoto, and Toshiyuki Takayanagi Org. Lett., 8, 91-94 (2006):
  5. vic-ジスルホキシド結合をもつ化合物の合成と性質 石井昭彦 有機合成化学協会誌,64,395-405(2006).
  6. Synthesis and reactions of a monosubstituted dithiirane 1-oxide, 3-(9-triptycyl)dithiirane 1-oxide. Akihiko Ishii, Tetsuhiko Kawai, Mariko Noji, and Juzo Nakayama Tetrahedron, 61, 6693-6699 (2005).
  7. Synthesis and Hydrolysis of p-Toluoyl and Acetyl 9-Triptycyl Diselenides: A Study on Generation of Triptycene-9-selenenoselenoic Acid. Akihiko Ishii, Yuichiro Mori, and Rei Uchiumi Heteroatom Chem., 16, 525-528 (2005).
  8. "First Isolation of Eclipsed vic-Disulfoxide: 7,8-Dithiabicyclo[4.2.1]nona-2,4-diene 7-exo, 8-exo-Dioxide", Akihiko Ishii, Satoshi Kashiura, Hideaki Oshida, and Juzo Nakayama, Org. Lett., 6, 2623-2626, 2004.
  9. "Oxidation of cis- and trans-3,5-Di-tert-butyl-3,5-diphenyl-1,2,4-trithiolanes: Isolation and Properties of the 1-Oxides and the 1,2-Dioxides", Hideaki Oshida, Akihiko Ishii, and Juzo Nakayama, J. Org. Chem., 69, 1695-1703, 2004.
  10. "First Isolation of 1,3,2-Dithiaphosphetane 2-Sulfide", Hideaki Oshida, Akihiko Ishii, and Juzo Nakayama, Tetrahedron Lett., 45, 1331-1334, 2004.
  11. "Pummerer Reaction of 4,7-Di-tert-butyl-3H,8H-1,2,5,6-dithiadiazocine 1-Oxide; Formation of 1,4-Dithiins", Juzo Nakayama, Shuhei Iida, Yoshiaki Sugihara, Akihiko Ishii, J. Sulf. Chem., 25, 13-19, 2004.
  12. "A. Reversible Disulfur Monoxide (S2O)-Forming Retro-Diels-Alder Reaction. Disproportionation of S2O to Trithio-Ozone (S3) and Sulfur Dioxide (SO2) and Reactivities of S2O and S3", Juzo Nakayama, Satoshi Aoki, Jun Takayama, Akira Sakamoto, Yoshiaki Sugihara, Akihiko Ishii, J. Am. Chem. Soc., 126, 9085-9093, 2004.
  13. "Oxosulfido Complexes of Platinum—(Ph3P)2Pt(S2O) and (Ph3P)4Pt2(μ-S)(μ-SO)—Their Formation and Properties", Akihiko Ishii, Masami Murata, Hideaki Oshida, Kimiyo Matsumoto, and Juzo Nakayama, Eur. J. Inorg. Chem., , 3716-3721, 2003.
  14. "Deoxygenation of Dithiirane 1-Oxides with Lawesson's Reagent Leading to the Corresponding Dithiiranes", Akihiko Ishii, Remi Yamashita, Masashi Saito, and Juzo Nakayama, J. Org. Chem., 68, 1555-1558, 2003.
  15. "Preparation of 1,4,5,8-Tetra-tert-butyl-1,3,5,7-cyclooctatetraene by Twofold SO2 Extrusion", Jun Takayama, Yoshiaki Sugihara, Akihiko Ishii, and Juzo Nakayama, Tetrahedron Lett., 44, 7893-7896, 2003.
  16. "Structures and Properties of Two Diastereomeric Sulfites Derived from cis-3,4-Di-tert-butylthiolane-3,4-diol and Thionyl Chloride", Sanae Tanaka, Yoshiaki Sugihara, Akira Sakamoto, Akihiko Ishii, and Juzo Nakayama, Heteroatom Chem., 14, 587-595, 2003.
  17. "π-Face-Selective Hetero Diels-Alder Reactions of 3,4-Di-tert-butylthiophene 1-Oxide. An Excellent Trapping Agent for Thioaldehydes and Thioketones", Jun Takayama, Seiko Fukuda, Yoshiaki Sugihara, Akihiko Ishii, and Juzo Nakayama, Tetrahedron Lett., 44, 5159-5162, 2003.
  18. "Regio- and Stereo-chemistry of Addition of Molecular Bromine to S-Oxidzed Derivatives of 3,4-Di-t-butylthiophene: Exclusive 1,4-Cis-additions", Juzo Nakayama, Tomohiro Furuya, Akihiko Ishii, Akihiko Sakamoto, Takashi Otani, and Yoshiaki Sugihara, Bull. Chem. Soc. Jpn., 76, 619-625, 2003.
  19. "Synthesis and Properties of Monocyclic 5H-1,2-Oxathioles (Cyclic α,β-Unsaturated Sulfenic Acid Esters)", Yutaka Ono, Yoshiaki Sugihara, Akihiko Ishii, and Juzo Nakayama, Bull. Chem. Soc. Jpn., 76, 613-617, 2003.
  20. "π-Face-Selective Diels-Alder Reactions of 3,4-Di-tert-butylthiophene 1-Oxide and 1-Imide and Formation of 1,2-Thiazetidines", Takashi Otani, Jun Takayama, Yoshiaki Sugihara, Akihiko Ishii, and Juzo Nakayama, J. Am. Chem. Soc., 125, 8255-8263, 2003.
  21. "The Thiosulfinyl Group Serves as a Stereogenic Center and Shows Diamagnetic Anisotropy Similar to the Sulfinyl Group", Sanae Tanaka, Yoshiaki Sugihara, Akira Sakamoto, Akihiko Ishii, and Juzo Nakayama, J. Am. Chem. Soc., 125, 9024-9025, 2003.
  22. "Synthesis and Characterization of Aliphtic α-Dithiones, Di(1-Adamantyl)- and Di-tert-butylethanedithiones", Yutaka Ono, Yoshiaki Sugihara, Akihiko Ishii, and Juzo Nakayama, J. Am. Chem. Soc., 125, 12114-12115, 2003.

科学研究費補助金

  1. 2007年度 特定領域研究 セレナメタラサイクルの創製と新合成反応への展開,石井昭彦,2,500千円
  2. 2003~4年度 基盤研究(C)(2) ヒドロジカルコゲニドの化学,石井昭彦,3,800千円
  3. 2006~7年度 若手研究(B) 4族遷移金属-シリレン錯体の創製とそれを触媒とする新規重合反応の開発 3,600千円

外部資金獲得状況

  1. 2007年度 財団法人井上科学振興財団 国際研究集会出席旅費援助 セレノセレニナートおよびその関連化合物の配位化学,中田憲男,200千円

受賞

  1. 有機合成化学協会 ADEKA研究企画賞 中田憲男